Solvent Extraction Studies of Copper from a Heap Leach Liquor Using Mextral 5640H

نویسندگان

چکیده

In this study the extractive capability of Mextral 5640H was investigated for extraction copper from a heap leach liquor. regard, influence parameters such as pH (0.2–2.8), extractant concentration in kerosene diluent (2.5%–10% v/v), temperature (25–70 °C), contact time (0–300 s), stirring speed (100–1200 rpm), phase ratio (O/A) (0.6–1.8) and Cu initial (0.5–2 g/L) liquor were examined optimized. The findings demonstrated that had very high efficiency selectivity leachate. 98.17% Cu, with less than 0.5% Fe Mn, extracted at 1.6, 10% (v/v) concentration, ambient (25 400 rpm speed, 2 min an O/A 1:1. Under equilibrium conditions it found one mol is by 7 5640H. Additionally, analysis using McCabe–Thiele diagram suggests two-stage to reach maximum (99.5%) leachate operational condition industrial mixer-settlers. Furthermore, thermodynamic conducted, measured values ΔH = 15.13 kJ/mol, ΔG −6.95 kJ/mol ΔS 74.10 J/mol/K indicate endothermic, spontaneous nature affinity extraction.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Solvent extraction of copper from an industrial sulfate liquor using Chemorex CP-150

The extraction behavior of Cu(II) ions from a real sulfate liquor obtained from the heap leaching stage of a copper oxide ore was investigated using a chelating reagent, Chemorex CP-150 in kerosene. A comparative study was also carried out on the extraction capability of Cu(II) ions using other solvents including D2EHPA and Cyanex 272.Chemorex CP-150 demonstrated an effective and selective extr...

متن کامل

Gallium extraction from Jajarm Bayer process liquor using micro-emulsions

Gallium extraction from Jajarm Bayer process liquor (Jajarm, Iran) was investigated using microemulsions. Also the behavior of aluminum was studied as an impurity. Kelex100 (4-ethyl, 1-methyl, 7-octyl, 8-hydroxyquinoleine), iso-decanol and n-butanol, and kerosene were used as the surfactant, co-surfactant, and oil phase, respectively. Ternary phase diagrams were produced using various co-surfac...

متن کامل

Purification of Sulphate Leach Liquor of Spent Raneynickel Catalyst Containing Al and Ni by Solvent Extraction with Organophosphorus-Based Extractants

Solvent extraction (SX) separation of Al from Ni sulphate leach liquor (LL) of spent Raneynickel catalyst containing 0.12 M Al and 1.448 M Ni using organophosphorus extractants has been investigated. Optimization of process conditions includes aqueous pH, extractant concentration, phase ratio, and stripping. Comparison of Al extraction efficiency with 0.45 M extractant concentration for TOPS 99...

متن کامل

Solvent extraction, spectrophotometric determination of copper (II) from environmental samples using o-methylphenyl thiourea as a novel reagent

A simple and rapid method has been developed for solvent extraction and spectrophotometric determination of copper (II) using o-methylphenyl thiourea (OMPT) as a sensitive reagent. The basis of proposed method is formation of copper (II)-OMPT complex. Copper (II) was extracted with 0.020 mol L-1 OMPT in chloroform from aqueous solution in 0.075 mol L-1 potassium iodate. The absorbance of comple...

متن کامل

Solvent Extraction Studies on Uranium using Amine Based Extractants and Recovery from Low Grade Ore Leach Liquors

Neste estudo, extratores à base de amina (Alamine 336, Alamine 308, Alamine 304 e Aliquat 336) diluídos em querosene foram usados para extração de urânio e separação de outros elementos associados. Alamine 336 foi o melhor extrator para o processo de extração de urânio de soluções de sulfato quando comparado com outros reagentes à base de amina, Alamine 308, 304 Alamine 336 e Aliquat 336. O com...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Minerals

سال: 2022

ISSN: ['2075-163X']

DOI: https://doi.org/10.3390/min12101322